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81.
Synthesis,spatial structure and spectral properties of pyrylo‐4 (thio) squaraines variously substituted in cyclobutene moiety 下载免费PDF全文
Vladimir V. Kurdyukov Aleksei I. Tolmachev Marina L. Dekhtyar Yurii G. Vlasenko Aleksandr N. Chernega 《Journal of Physical Organic Chemistry》2015,28(7):452-459
Synthetic routes have been developed to a number of (thio) squaraine dyes containing the residues of CH‐acids at the central cyclobutene ring. The electronic and spatial structure as well as the chemical conversions and optical behaviour of the compounds obtained have been studied both theoretically and by X‐ray diffraction analysis, 1H NMR and electronic spectroscopy. As shown, the electronic nature and sterical characteristics of the central ring substituents give rise to some general conformational features and crystal packing regularities and also govern the spectral position of the first π–π* absorption band. The structure–property relationships established in the study provide guidance for the purposeful design of deeply coloured (thio) squaraines. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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It is well known (after Rayleigh) that a plan-parallel flow in a channel can be unstable only if the basic velocity profile U(z) possesses inflection points. The profile determines (via the Rayleigh equation) the maximal increment c
i of small perturbations and 'eigenvalues' c (see Equation (1)). The increment and the imaginary parts c
i of the eigenvalues c provide a quantitative characterization of the basic stability properties of the flow. Here we find some best possible bounds for these values. The bounds are determined by the following parameters: wave number ; enstrophy
of the basic flow; width of the channel L. A similar approach can be applied to models of atmosphere, ocean, plasma etc. 相似文献
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Sergey?V.?Alekseenko Vladimir?M.?Dulin Yuriy?S.?Kozorezov Dmitriy?M.?MarkovichEmail author Sergey?I.?Shtork Mikhail?P.?Tokarev 《Flow, Turbulence and Combustion》2011,87(4):569-595
Flow structure of premixed propane–air swirling jet flames at various combustion regimes was studied experimentally by stereo
PIV, CH* chemiluminescence imaging, and pressure probe. For the non-swirling conditions, a nonlinear feedback mechanism of
the flame front interaction with ring-like vortices, developing in the jet shear layer, was found to play important role in
the stabilisation of the premixed lifted flame. For the studied swirl rates (S = 0.41, 0.7, and 1.0) the determined domain of stable combustion can be divided into three main groups of flame types: attached
flames, quasi-tubular flames, and lifted flames. These regimes were studied in details for the case of S = 1.0, and the difference in the flow structure of the vortex breakdown is described. For the quasi-tubular flames an increase
of flow precessing above the recirculation zone was observed when increased the stoichiometric coefficient from 0.7 to 1.4.
This precessing motion was supposed to be responsible for the observed increase of acoustic noise generation and could drive
the transition from the quasi-tubular to the lifted flame regime. 相似文献
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Bumagin Nikolay A. Petkevich Sergey K. Kletskov Alexey V. Alekseyev Roman S. Potkin Vladimir I. 《Chemistry of Heterocyclic Compounds》2019,55(6):508-516
Chemistry of Heterocyclic Compounds - N-(4,6-Dimethylpyrimidin-2-yl)-5-phenylisoxazole-3-carboxamide was used as a ligand for obtaining bimetallic boron-containing heterogeneous catalysts... 相似文献
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Zhu Wu Jrn Nitsch Julia Schuster Alexandra Friedrich Katharina Edkins Marcel Loebnitz Fabian Dinkelbach Vladimir Stepanenko Frank Würthner Christel M. Marian Lei Ji Todd B. Marder 《Angewandte Chemie (International ed. in English)》2020,59(39):17137-17144
Achieving highly efficient phosphorescence in purely organic luminophors at room temperature remains a major challenge due to slow intersystem crossing (ISC) rates in combination with effective non‐radiative processes in those systems. Most room temperature phosphorescent (RTP) organic materials have O‐ or N‐lone pairs leading to low lying (n, π*) and (π, π*) excited states which accelerate kisc through El‐Sayed's rule. Herein, we report the first persistent RTP with lifetimes up to 0.5 s from simple triarylboranes which have no lone pairs. RTP is only observed in the crystalline state and in highly doped PMMA films which are indicative of aggregation induced emission (AIE). Detailed crystal structure analysis suggested that intermolecular interactions are important for efficient RTP. Furthermore, photophysical studies of the isolated molecules in a frozen glass, in combination with DFT/MRCI calculations, show that (σ, B p)→(π, B p) transitions accelerate the ISC process. This work provides a new approach for the design of RTP materials without (n, π*) transitions. 相似文献